AP Chemistry Concept List
This file contains 500 concepts for the AP Chemistry learning graph, organized by course unit with foundational and cross-cutting concepts.
Foundational Concepts (1-25)
- Matter
- Energy
- Atoms
- Elements
- Compounds
- Mixtures
- Physical Properties
- Chemical Properties
- Physical Changes
- Chemical Changes
- Scientific Method
- Measurement
- SI Units
- Significant Figures
- Dimensional Analysis
- Density
- Temperature Scales
- Scientific Notation
- Accuracy and Precision
- Percent Error
- Laboratory Safety
- Data Collection
- Graphing Data
- Conservation Laws
- Atomic Theory History
Unit 1: Atomic Structure and Properties (26-80)
- Subatomic Particles
- Protons
- Neutrons
- Electrons
- Atomic Number
- Mass Number
- Isotopes
- Atomic Mass
- Average Atomic Mass
- Mass Spectrometry
- Mass Spectrum Analysis
- Relative Abundance
- Mole Concept
- Avogadro's Number
- Molar Mass
- Mole Calculations
- Percent Composition
- Empirical Formula
- Molecular Formula
- Combustion Analysis
- Bohr Model
- Quantum Mechanical Model
- Energy Levels
- Principal Quantum Number
- Subshells
- Orbitals
- Orbital Shapes
- Electron Configuration
- Aufbau Principle
- Pauli Exclusion Principle
- Hund's Rule
- Valence Electrons
- Core Electrons
- Noble Gas Notation
- Electron Config of Ions
- Electromagnetic Spectrum
- Wavelength
- Frequency
- Photon Energy
- Planck's Equation
- Photoelectric Effect
- Emission Spectra
- Absorption Spectra
- Photoelectron Spectroscopy
- PES Data Interpretation
- Periodic Table Organization
- Periods and Groups
- Periodic Trends
- Atomic Radius
- Ionic Radius
- Ionization Energy
- Successive Ionization Energy
- Electron Affinity
- Electronegativity
- Effective Nuclear Charge
Unit 2: Molecular and Ionic Compound Structure (81-140)
- Chemical Bonds
- Ionic Bonds
- Covalent Bonds
- Metallic Bonds
- Bond Formation Energy
- Ionic Compounds
- Crystal Lattice
- Lattice Energy
- Cation Formation
- Anion Formation
- Polyatomic Ions
- Naming Ionic Compounds
- Writing Ionic Formulas
- Transition Metal Ions
- Lewis Dot Symbols
- Lewis Structures
- Octet Rule
- Single Bonds
- Double Bonds
- Triple Bonds
- Lone Pairs
- Bonding Pairs
- Resonance Structures
- Resonance Hybrid
- Formal Charge
- Formal Charge Calculation
- Expanded Octets
- Incomplete Octets
- Exceptions to Octet Rule
- Bond Order
- Bond Length
- Bond Energy
- VSEPR Theory
- Electron Geometry
- Molecular Geometry
- Linear Geometry
- Trigonal Planar Geometry
- Tetrahedral Geometry
- Trigonal Bipyramidal
- Octahedral Geometry
- Bent Geometry
- Trigonal Pyramidal
- Bond Angles
- Lone Pair Repulsion
- Orbital Hybridization
- sp Hybridization
- sp2 Hybridization
- sp3 Hybridization
- Sigma Bonds
- Pi Bonds
- Bond Polarity
- Electronegativity Difference
- Polar Covalent Bonds
- Nonpolar Covalent Bonds
- Dipole Moment
- Molecular Polarity
- Polar Molecules
- Nonpolar Molecules
- Naming Covalent Compounds
- Network Covalent Solids
Unit 3: Intermolecular Forces and Properties (141-200)
- Intermolecular Forces
- Intramolecular Forces
- IMF vs Chemical Bonds
- London Dispersion Forces
- Polarizability
- Dipole-Dipole Forces
- Hydrogen Bonding
- Hydrogen Bond Requirements
- Ion-Dipole Forces
- IMF Strength Comparison
- States of Matter
- Kinetic Molecular Theory
- Solids
- Crystalline Solids
- Amorphous Solids
- Liquids
- Surface Tension
- Viscosity
- Capillary Action
- Gases
- Gas Pressure
- Atmospheric Pressure
- Ideal Gas Law
- Ideal Gas Constant
- Boyle's Law
- Charles's Law
- Avogadro's Law
- Dalton's Law
- Partial Pressures
- Mole Fraction
- Gas Stoichiometry
- Molar Volume
- Real Gases
- Van der Waals Equation
- Deviations from Ideality
- Phase Changes
- Melting and Freezing
- Boiling and Condensation
- Sublimation and Deposition
- Heating Curves
- Cooling Curves
- Heat of Fusion
- Heat of Vaporization
- Phase Diagrams
- Triple Point
- Critical Point
- Vapor Pressure
- Solutions
- Solvent and Solute
- Solubility
- Like Dissolves Like
- Saturated Solutions
- Concentration Units
- Molarity
- Dilution Calculations
- Beer-Lambert Law
- Spectrophotometry
- Colligative Properties
- Boiling Point Elevation
- Freezing Point Depression
Unit 4: Chemical Reactions (201-265)
- Chemical Equations
- Balancing Equations
- Coefficients
- State Symbols
- Reaction Types Overview
- Synthesis Reactions
- Decomposition Reactions
- Single Replacement
- Double Replacement
- Combustion Reactions
- Activity Series
- Solubility Rules
- Precipitation Reactions
- Complete Ionic Equations
- Net Ionic Equations
- Spectator Ions
- Stoichiometry
- Mole-to-Mole Ratios
- Mass-to-Mass Calculations
- Limiting Reagent
- Excess Reagent
- Theoretical Yield
- Actual Yield
- Percent Yield
- Solution Stoichiometry
- Titration
- Titration Curves
- Equivalence Point
- Indicator Selection
- Gravimetric Analysis
- Oxidation States
- Assigning Oxidation Numbers
- Oxidation
- Reduction
- Redox Reactions
- Half Reactions
- Balancing Redox Equations
- Oxidizing Agents
- Reducing Agents
- Electron Transfer
- Conservation of Mass
- Conservation of Charge
- Gas Evolution Reactions
- Acid-Carbonate Reactions
- Molecular Equations
- Reaction Prediction
- Qualitative Analysis
- Flame Tests
- Precipitate Identification
- Volumetric Analysis
- Standard Solutions
- Primary Standards
- Endpoint vs Equivalence
- Titration Calculations
- Percent Purity
- Empirical Formula from Data
- Molar Ratios in Solutions
- Serial Dilutions
- Driving Force of Reactions
- Metathesis Reactions
- Acid-Metal Reactions
- Disproportionation
- Color of Solutions
- Chemical Analysis
- Back Titration
Unit 5: Kinetics (266-320)
- Reaction Rate
- Rate of Disappearance
- Rate of Appearance
- Average Rate
- Instantaneous Rate
- Initial Rate
- Rate Law
- Rate Constant
- Reaction Order
- Zero Order Reactions
- First Order Reactions
- Second Order Reactions
- Determining Reaction Order
- Method of Initial Rates
- Integrated Rate Laws
- Zero Order Integrated Law
- First Order Integrated Law
- Second Order Integrated Law
- Half-Life
- First Order Half-Life
- Graphical Rate Analysis
- Concentration vs Time
- Linearization Rate Data
- Collision Theory
- Activation Energy
- Activated Complex
- Transition State
- Effective Collisions
- Orientation Factor
- Arrhenius Equation
- Arrhenius Plot
- Frequency Factor
- Temperature and Rate
- Energy Diagrams
- Exothermic Diagrams
- Endothermic Diagrams
- Reaction Mechanisms
- Elementary Steps
- Molecularity
- Unimolecular Reactions
- Bimolecular Reactions
- Rate-Determining Step
- Reaction Intermediates
- Mechanism Validation
- Catalysis
- Homogeneous Catalysis
- Heterogeneous Catalysis
- Enzyme Catalysis
- Catalyst Effect on Ea
- Catalyst and Equilibrium
- Catalyzed vs Uncatalyzed
- Surface Area and Rate
- Concentration and Rate
- Factors Affecting Rate
- Kinetics Experiments
Unit 6: Thermodynamics (321-375)
- Thermodynamics
- System and Surroundings
- Open Systems
- Closed Systems
- Isolated Systems
- Exothermic Reactions
- Endothermic Reactions
- Heat and Temperature
- Heat Transfer
- Specific Heat Capacity
- Heat Capacity
- Calorimetry
- Coffee Cup Calorimeter
- Bomb Calorimeter
- Enthalpy
- Enthalpy Change
- Standard Enthalpy
- Enthalpy of Formation
- Standard Formation Values
- Enthalpy of Combustion
- Enthalpy of Reaction
- Hess's Law
- Hess's Law Calculations
- Born-Haber Cycle
- Bond Enthalpy
- Bond Enthalpy Calculations
- Entropy
- Entropy Change
- Standard Entropy
- Entropy and Disorder
- Microstates
- Boltzmann Equation
- Second Law Thermodynamics
- Third Law Thermodynamics
- Entropy of Phase Changes
- Entropy Predictions
- Gibbs Free Energy
- Gibbs Free Energy Equation
- Standard Free Energy
- Free Energy of Formation
- Spontaneity
- Nonspontaneous Processes
- Temperature Dependence
- Gibbs and Equilibrium
- Free Energy and Work
- Coupled Reactions
- Thermodynamic Stability
- Kinetic Stability
- State Functions
- Path Functions
- Internal Energy
- First Law Thermodynamics
- PV Work
- Enthalpy vs Internal Energy
- Calorimetry Calculations
Unit 7: Equilibrium (376-420)
- Chemical Equilibrium
- Dynamic Equilibrium
- Equilibrium State
- Forward Reaction
- Reverse Reaction
- Equilibrium Constant Kc
- Equilibrium Constant Kp
- Kc and Kp Relationship
- Writing K Expressions
- Homogeneous Equilibrium
- Heterogeneous Equilibrium
- Equilibrium Position
- Reaction Quotient Q
- Q vs K Comparison
- Predicting Direction
- ICE Tables
- ICE Table Calculations
- Small K Approximation
- Quadratic in Equilibrium
- Le Chatelier's Principle
- Concentration Changes
- Pressure Changes
- Volume Changes
- Temperature Changes on K
- Effect of Catalyst on Eq
- Adding Inert Gas
- Equilibrium Shifts
- Solubility Equilibria
- Solubility Product Ksp
- Molar Solubility
- Common Ion Effect
- Predicting Precipitation
- Selective Precipitation
- Complex Ion Formation
- Formation Constants
- Ksp Calculations
- Ion Product
- Temperature and Solubility
- Henry's Law
- Equilibrium and Free Energy
- Relationship K and Delta G
- Manipulating K Expressions
- Reversing Reactions K
- Adding Reactions K
- Industrial Equilibrium
Unit 8: Acids and Bases (421-475)
- Acids
- Bases
- Arrhenius Theory
- Bronsted-Lowry Theory
- Lewis Acid-Base Theory
- Conjugate Acid-Base Pairs
- Conjugate Acid
- Conjugate Base
- Amphiprotic Substances
- Autoionization of Water
- Ion Product of Water Kw
- pH Scale
- pH Calculation
- pOH
- pH and pOH Relationship
- Strong Acids
- Strong Bases
- Strong Acid pH
- Strong Base pH
- Weak Acids
- Weak Bases
- Acid Dissociation Ka
- Base Dissociation Kb
- Ka and Kb Relationship
- Percent Ionization
- Weak Acid pH Calculation
- Weak Base pH Calculation
- Polyprotic Acids
- Diprotic Acid Equilibria
- Acid Strength Factors
- Binary Acid Trends
- Oxyacid Strength
- Salt Hydrolysis
- Acidic Salts
- Basic Salts
- Neutral Salts
- Buffer Solutions
- Buffer Composition
- Henderson-Hasselbalch
- Buffer Capacity
- Buffer pH Calculations
- Buffer Preparation
- Acid-Base Titration
- Strong Acid-Strong Base
- Weak Acid-Strong Base
- Strong Acid-Weak Base
- Titration Curve Analysis
- Half-Equivalence Point
- Buffer Region
- Indicators and pH Range
- Selecting Indicators
- Neutralization Reactions
- Net Ionic Acid-Base
- Dilute Acid Calculations
- pH of Mixed Solutions
Unit 9: Applications of Thermodynamics / Electrochemistry (476-500)
- Electrochemistry
- Galvanic Cells
- Voltaic Cell Components
- Anode and Cathode
- Salt Bridge
- Electron Flow Direction
- Cell Notation
- Standard Reduction Potential
- Standard Hydrogen Electrode
- Cell Potential Calculation
- Spontaneous Cell Reactions
- Nernst Equation
- Nonstandard Conditions
- Concentration Cells
- Free Energy and Cell EMF
- Delta G and E Relation
- Faraday's Constant
- Electrolytic Cells
- Electrolysis
- Electrolysis of Water
- Electroplating
- Faraday's Laws
- Stoichiometry Electrolysis
- Batteries and Fuel Cells
- Corrosion
Addendum: Concepts from Bloom's Taxonomy Learning Objectives (501-508)
These concepts are explicitly named in the course description's Bloom's Taxonomy learning objectives but were not included in the original 500-concept learning graph. They are covered in the chapters indicated.
- Coulombic Attraction
- Molecular Orbital Theory
- Bonding Molecular Orbitals
- Antibonding Molecular Orbitals
- MO Energy Diagrams
- Bond Order from MO Theory
- Paramagnetism and Diamagnetism
- Error Propagation